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malonic anhydride : ウィキペディア英語版
malonic anhydride

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Malonic anhydride or oxetane-2,4-dione is an organic compound with chemical formula C3H2O3 or CH2(CO)2O. It can be viewed as the anhydride of malonic acid, or a double ketone of oxetane.
Malonic anhydride was first synthesized in 1988 by ozonolysis of diketene.〔
Cotton, F. A.; Wilkinson, G. (1988) ''Advanced Inorganic Chemistry'', 5th edn. Wiley
〕〔

〕 Some derivatives, such as 3,3-dimethyl-oxetane-2,4-dione, are known.〔
Charles L. Perrin; Arrhenius, T (1978). J. Am. Chem. SOC. volume 100, pages 5249-5251.
〕〔
Ribeiro da Silva, M. A. J.; Monte, M. J. S.; Ribeiro, J. R.(1999) ''J. Chem.Thermodyn.'' 31, 1093.
〕〔
Charles L. Perrin, Douglas Magde, Sylvia J. Berens, Julie Roque (1980), ''Raman spectrum of a malonic anhydride''. (Actually, of 3,3-dimethyl-oxetane-2,4-dione.) J. Org. Chem., volume 45 issue 9, pp 1705–1706. .

==References==


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